// This Code is working properly
// Just Copy and paste it
AutoCompleteStringCollection ac = new AutoCompleteStringCollection();
foreach (DataRow row in MyDatatable.Rows)
{
//looping through the datatable and adding values from datatable into autocomplete collection
ac.Add(row["CustName"].ToString());
}
comboCustomerName.AutoCompleteSource = AutoCompleteSource.CustomSource; //assigning
// autocomplete source to the combobox
comboCustomerName.AutoCompleteCustomSource = ac;